منابع مشابه
N-Phenyladamantane-1-sulfinamide
In the racemic title compound, C(16)H(21)NOS, the mol-ecules are packed into polymeric chains in the b-axis direction and are linked along the b axis by N-H⋯O and C-H⋯O hydrogen bonds.
متن کامل(S)-N-[(1S,2S)-2-Benzylamino-1-(4-hydroxyphenyl)-3-methylbutyl]-1,1-dimethylethane-2-sulfinamide
The title compound, C(22)H(32)N(2)O(2)S, was obtained by dehydroxy-lation and deacetyl-ation of 4-{(1S,2S)-2-(benzylhydroxy-amino)-3-methyl-1-[(S)-2-methyl-propane-2-sulfinylamino]but-yl}phenyl acetate, which was derived from reductive crosslinking of nitrone with N-tert-butane-sulfinyl-imine. The crystal structure shows that the mol-ecules are linked by O-H⋯O hydrogen bonds.
متن کاملMethemoglobin oxidation of N-acetylbenzidine to form a sulfinamide.
Aromatic amine sulfinamide adducts of hemoglobin are biomarkers of exposure and evidence for cytochrome P-450 N-hydroxylation. The possible peroxidatic formation of an N-acetylbenzidine (ABZ) sulfinamide adduct by methemoglobin was examined. Following addition of H2O2, 0.06 mM [3H]ABZ was metabolized by methemoglobin. With 0.3 mM glutathione, a new peak was observed, ABZ-SG, representing 17% of...
متن کاملBis{(R)-N-[(R)-2-benzyloxy-1-(4-tert-butylphenyl)ethyl]-2-methylpropane-2-sulfinamide} monohydrate
The asymmetric unit of the title compound, 2C23H33NO2S·H2O, contains one organic mol-ecule in a general position and one co-crystallized water mol-ecule on a crystallographic twofold axis. Each water mol-ecule serves as a hydrogen-bond donor to a pair of S=O acceptors on symmetry-related mol-ecules. Thus, each trio of mol-ecules forms one title formula unit. These groupings are further connecte...
متن کامل(R)-N-[(R)-2,2-Dichloro-1-phenyl-2-(phenylsulfonyl)ethyl]-2-methylpropane-2-sulfinamide
The title mol-ecule, C18H21Cl2NO3S2, contains one chiral carbon center and the absolute sterochemistry has been confirmed as as R. An intra-molecular N-H⋯O hydrogen bond occurs and the dihedral angle between the benzene rings is 64.5 (1)°. In the crystal, the mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming a zigzag chain structure extending along the c-axis direction.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808019570